抄録
6-exo-Acetoxy-exo-isocamphane [ 5 ] was stereospecifically given in 18% yield (GLC; isolated yield was 7.5%) by Bertram-Walbaum hydration of camphene [1].6-exo-Hydroxy-exo-isocamphane [ 6 ] was obtained by hydrolysis of [ 5 ], and 6-endo-hydroxy-exo-isocamphane [ 8 ] was derived by dehydrogenation of [ 6 ], followed by LiAlH4 reduction. The structures of [5 ]-[8 ] were assigned on the basis of their MS, IR, NMR spectra and their authentic data. Compound [ 6 ] has such elegant odor as nojigiku alcohol [10], but [ 8 ] has an odor like borneol.
