ヒドラジノ-1,3,5-トリアジンの酸化

抄録

Oxidation of hydrazino-1, 3, 5-triazine [1] with s everal oxidizing agents was investigated. Oxidation of [1] with nitrous acid in aqueous-chloroform media afforded triazinyl azide [2] as the sole product. On the other hand, the oxidation with such agents as mercury(II)oxide, irona(III) chloride, or bromine afforded chloro- [3], hydrazo- [4], bromo- [ 6 ], hydroxytriazine [7] and triazine [ 5 ] as products, depending on the oxidizing agent and the conditions employed. The formation of these products can be explained in terms of the formation of triazinyldiazene and its subsequent oxidation to triazinediazonium ion as reaction intermediates.