In recent years, the functional oxide thin films and their heterostructures have demonstrated a range of surprising properties. Here, we present insights into the atom-by-atom growth of oxide thin films, and further reveal the unique electronic properties on the SrTiO3 surface. Given the wide range of compositions these oxides can span, it is expected that more functionalities can be discovered through the atomic-scale in situ investigation of surfaces and growths using high-resolution scanning tunneling microscopy/spectroscopy (STM/STS).