A07 CNF分散液と超音波を用いたリチウムイオン電他用正極材料LiFePO_4の合成

抄録

Lithium iron phosphate has attracted attention as a promising cathode material for lithium ion battery, because of its less expensive, abundance. However, the battery capability of this material is at present limited by its low electronic conductivity and low lithium diffusion rate. In order to improve the poor diffusion of lithium ions and the low electronic conductivity, mainly two possible approaches have been studied. One is to increase the surface area of active materials which can reduce the ion-diffusion pathway, and the other is to deposit conductive carbon layers on the surface to improve electronic conductivity. Since the surface area is dependent on the particle size of LiFePO_4, the synthetic method is very important to control the particle size. In this study, Olivine-type LiFePO_4 was prepared via a Sonochemical reaction to gain the fine particles. LiOH・H_2O, (NH_4)_2HPO_4 and FeSO_4・7H_2O were used as the starting materials. An Alcohol was added to the solution of the raw materials. When ultrasonic irradiation upon an alcohol, it is so effective for prohibition of conversion from Fe^<2+> to Fe^<3+> in the solution without reducing agent. The precipitate prepared from the solution gave fine particles of LiFePO_4 after calcination. The LiFePO_4 powders obtained was of homogeneity and globular structure with sub-micron particle sizes. In addition, we examined the application of CNF as a conductive carbon to improve the electronic conductivity of LiFePO_4.