ソノケミストリー討論会講演論文集
Online ISSN : 2424-1512
セッションID: A16
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A16 超音波による定在波場を利用したグリシンの結晶化挙動
*二井 晋作本 祐一郎水田 敬五島 崇
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Anti-solvent crystallization of glycine was conducted under a standing-wave field given by 5.0 MHz ultrasound. Columnar crystals of Glycine were fixed at each three dimensional lattice points with directing their longer axis horizontally. The crystals were vibrating around the lattice points. Ultrasound helped to pin and to orient the crystal at lattice points within liquids. Crystals located in the lattice points grow with irradiation time. However, the size uniformity was less enhanced unlike our previous study under the irradiation of 1.6 MHz ultrasound coupled with a mechanical stirring. The result shows that the unique behavior of glycine crystals under a standing wave field brought about less uniform crystal growth. While, the characteristics of crystal orientation helped to grow uniquely-shaped crystal. Multiple columnar crystals stuck together at their sidewalls.
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