Preparation of organic derivatives of layered perovskite using n-alkylamine layered perovskite intercalation compounds as intermediates

Abstract

The alkoxyl derivatives of layered perovskite, H_1.8Sr_0.8Bi_0.2Ta₂O₇, were prepared using n-alkylamine layered perovskite intercalation compounds as intermediates. After the reaction of n-alkylamine intercalation compound of HST with n-decanol in an autoclave at 150°C the basal spacing increased. Carbon-13 NMR showed the presence of signals due to n-decoxyl groups and downfield shift of a a-carbon signal, indicating of the formation of Ta-O-C bond. These results suggest successful modification of H_1.8Sr_0.8Bi_0.2Ta₂O₇.