Preparation of Two-dimensional Inorganic-Organic Hybrids via Interlayer Surface Modification of Ion-exchangeable Layered Perovskites

Abstract

Interlayer surface modification of portonated forms of ion-exchangeable layered perovskites, HLaNb₂O₇^.xH₂O and HCa₂Nb₃O₁₀^.xH₂O was performed. Bulky alcohols, which did not react directly, can be dissociateively immobilized using appropriate intermediate alkoxyl derivatives. Furthermore, interlayer surface can be modified with trifluoroacetic acid and silanol-terminated polydimethylsiloxane. It was possible to conduct hydrosilylation between immobilized C=C groups and hydrosilanes in the interlayer space.