抄録
The phosphorylation of amino alcohols has been achieved using inorganic sodium cyclo-triphosphate hexahydrate, Na3P3O9·6H2O, in aqueous solution. The main phosphorylated products were imidotriphosphates of amino alcohols as evidenced by 1H, 13C, and 31P NMR spectra. In the phosphorylation of 3-amino-1-propanol (3A1P), 4-amino-1-butanol (4A1B), and 5-amino-1-pentanol (5A1P), only their amino groups were phosphorylated to give imidotriphosphates, with their maximum yields of more than 97%.
