Phosphorus Research Bulletin
Online ISSN : 1882-2363
Print ISSN : 0918-4783
ISSN-L : 0918-4783
THE SYNTHESIS AND THERMAL BEHAVIOUR OF CYCLO-IMIDO-PHOSPHATES
MAKOTO SAKURAIMIOKO MAEDAMAKOTO WATANABE
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ジャーナル フリー

2002 年 13 巻 p. 205-208

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抄録
Cyclo-tri- and tetra- μ-imido-tetraphosphate has been prepared by adding aqueous sodium acetate into a cyclo-tri- and tetraphosphazenes solution. When the sodium cyclo-tri- and tetra- μ-imido-tri- and tetraphosphate was dissolved in a acidic solution, substitution from imino group to bridging oxygen and white precipitate of imido phosphoric acid were observed. When the imidophosphates were heated, decomposition to produce many kinds of condensed phosphates with or without NH and NH2 groups at a higher temperature were occured.
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© Japanese Association of Inorganic Phosphorus Chemistry
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