Phosphorus Research Bulletin
Online ISSN : 1882-2363
Print ISSN : 0918-4783
ISSN-L : 0918-4783
CHEMICAL PREPARATION AND CRYSTAL DATA FOR TWO CONDENSED PHOSPHATES NiCs4(PO3)6 AND NiK4(P3O9)2
KACEM SBAIAZEDDINE ATIBIABDELKEBIR KENZELMOSTAFA TACEMALIKA TRIDANE
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2003 年 16 巻 p. 107-111

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Methods of chemical preparation and crystallographic data are reported for two new condensed phosphates: a polyphosphate of nickel and cesium, NiCs4(PO3)6, and a cyclotriphosphate of nickel and potassium, NiK4(P3O9)2. NiCs4(PO3)6 is rhombohedral with the following unit-cell dimensions: a=b=11.602(1)Å, c=9.078(1)Å, space group P-31c, V=1058.24(1)Å3 and Z=2. NiK4(P3O9)2 is triclinic with the following unit-cell dimensions: a=6.143(8)Å, b=6.80(1)Å, c=12.80(3)Å, α=102.8(3)°, β=89.7(2)°, γ=66.03(7)°, space group P-1, V=473.56(3)Å3 and Z=1.

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© Japanese Association of Inorganic Phosphorus Chemistry
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