Phosphorus Research Bulletin
Online ISSN : 1882-2363
Print ISSN : 0918-4783
ISSN-L : 0918-4783
EVIDENCE FOR THE FORMATION OF HIGHER cyclo-POLYPHOSPHATES AS DEGRADATION PRODUCTS OF LINEAR OCTAPHOSPHATE
GENICHIRO KURA
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ジャーナル フリー

1994 年 4 巻 p. 105-110

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Degradation products of cyclo-octaphosphate and linear octaphosphate under several conditions were analyzed using the liquid chromatographic system recently devised by us. cyclo-Polyphosphates larger than tetramer, cyclo-penta- and -hexaphosphate were found in the degradation products in weakly acidic media and in the presence of Al3+ and Cu2+ ions. The mechanism of these cyclo-polyphosphate abstractions in the hydrolysis reactions of octaphosphate is discussed.
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© Japanese Association of Inorganic Phosphorus Chemistry
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