Review of Polarography
Online ISSN : 1884-7692
Print ISSN : 0034-6691
ISSN-L : 0034-6691
Standard Electrode Potentials of R--/R+ Redox Couples and Medium Effects in Non-aqueous Solvents
Mitsugi SENDARelji TAKAHASHI
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1974 年 20 巻 4-6 号 p. 56-60

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The standard electrode potentials of R-/R+ redox couples may be estimated from polarographic reversible half-wave potentials of R/R+ and R-/R couples. When R+ and R- are large ions, similar in size and structure, the standard potential may be assumed as a solvent-independent reference point of electrode potential in various solvents. A few possible candidates for the "reference redox couple" have been discussed.
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© The Polarographic Society of Japan
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