Formation of organic base group into olefinic group on mesoporous silica

Abstract

Several organic groups have been added to olefinic Group introduced on mesoporous silica. The Introduction of Olefinic Group was carried out by the reaction of Allyl magnesium chloride with Si-Cl group which was formed by substitution of silanol group on mesoporous silica. In this work, amino group was carried out by the radical brominatio of hydrobromic acid with olefin on SBA-15 and MCM-41, followed by the reatment of organic amine or ammonia.