金属表面技術
Online ISSN : 1884-3395
Print ISSN : 0026-0614
ISSN-L : 0026-0614
破砕ヤシ殼活性炭による光沢ニッケルメッキ液中の有機物の収着除去
光沢ニッケルメッキの性状におよぼす主要因の研究 (第4報)
永井 淑晴杉山 卓之輔柳原 護斉藤 昭三矢作 充由
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1970 年 21 巻 4 号 p. 171-176

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The sorption of coconut-core active carbon for automatic elimination of organic impurities, oxidized or reduced substances of 2-butyne-1·4-diol, in bright nickel plating bath was investigated.
The results obtained were as follows:
1) The sorption points of acidic impurities and alcoholic ones were different each other.
2) Much more 2-butyne-1·4-diol (brightener) was sorbed than its oxidized or reduced substances (acidic or alcoholic impurities).
3) The process of automatic or semi-automatic elimination of the organic impurities was preferable to conduct in the following order of sequence.
(a) Passing through 30g/l of coconut-core active carbon of 30-50 mesh about 5 times for elimination of the brightener.
(b) Adding 0.1g/l of KMnO4 to the solution.
(c) Dissolving the precipitate obtained (MnO2) with 0.143ml/l of 30% H2O2.
(d) Passing through the active carbon layer, used in the process of (a), more than 9 times for more than 1hr.
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