金属表面技術
Online ISSN : 1884-3395
Print ISSN : 0026-0614
ISSN-L : 0026-0614
アンモニアアルカリ性浴からの無電解ニッケル-スズ-リン合金めっきについて
青木 公二鷹野 修石橋 知林 忠夫
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1977 年 28 巻 12 号 p. 629-633

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A study has been made of the effect of tin and phosphorus content of the bath on the properties of electroless nickel-tin-phosphorus alloy deposits obtained from ammonia alkaline bath. The alloy deposits containing up to 1.0% tin and 3.4-5.4% phosphorus can be obtained by an addition of sodium stannate to the plating bath. The deposition rate of the alloy containing 0.25% tin was the lowest, because tin reacted as an inhibitor on the nickel surface. It was also found that the corrosion resistance of the nickel-tin-phosphorus deposit containing 0.46% tin and 3.97% phosphorus was most enhanced in 1N sulfuric acid by the presence of tin and phosphorus.
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