金属表面技術
Online ISSN : 1884-3395
Print ISSN : 0026-0614
ISSN-L : 0026-0614
硫酸ニッケル水溶液中でアルミニウム陽極酸化皮膜をカソード分極している時のインピーダンス変化
佐藤 敏彦酒井 茂
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1978 年 29 巻 11 号 p. 595-599

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Impedance of aluminum oxide films anodized in a sulfuric acid bath is measured in nickel sulfate-boric acid mixed aqueous solution. When the oxide films are not cathodically polarized, the measured impedance is mainly the impedance of barrier layer, and the phase angle is 84°. This impedance is a capasitive impedance. When cathodic voltage is applied on the oxide films, the impedance suddenly decreases. During cathodic polarization, the impedance gradually increases and phase angles are in the range between 10°to 40°. This impedance is ohmic impedance. Separation of non-Faradic impedance and Faradic impedance was impossible in this study.
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