Journal of The Surface Finishing Society of Japan
Online ISSN : 1884-3409
Print ISSN : 0915-1869
ISSN-L : 0915-1869
Electrodeposition of Flexible V2Ox/PPTA Composite Film and Electrochromic Properties
Sumio YAMASAKIMasahiro UENOKatsuharu SHIMADAYasuhiro SOEJIMAHiroki OHURASumiaki TSURU
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1998 Volume 49 Issue 9 Pages 990-995

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Abstract
V2Ox/PPTA composite film consisting of vanadium oxide (V2Ox) and poly (p-phenylene terephthalamide) (PPTA) was prepared on ITO glass-coated with PPTA as described in the previous paper for WO3/PPTA film.
Electrochemical, elctrochromic, and mechanical studies showed that V2Ox/PPTA film had essentially the same electrochemical and electrochromic properties as V2Ox film, but much greater mechanical strength (tensile strength: 86.3MPa, tensile modulus: 4.35GPa) and flexibility. We also found that V2Ox film prepared this way was amorphous; on cathodic polarization, the color reversibly changed to green and on anodic polarization to yellow. If it acquires other intermediate colors as different potentials are applied, it may be used as a multicolor indicator.
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