1982 年 98 巻 1131 号 p. 436-440
The distributions of As, Sb and Bi between molten copper and white metal were separately investigated at varying element concentrations and temperatures. Distribution coefficients for all three elements, defined as solubility in copper divided by solubility in white metal, were found to be greater than unity and to decrease with increasing concentrations of the elements in copper and/or with increasing temperature. A tentative thermodynamic explanation of the influence of concentration changes of the elements is presented.