日本鉱業会誌
Online ISSN : 2185-6729
Print ISSN : 0369-4194
石炭の酸化反応におよぼす界面活性剤の影響
自然発火抑制のための炭壁注入剤の研究 (第1報)
大塚 一雄宮腰 宏佐藤 博佐藤 勇加藤 春実小田 仁平次近藤 善資
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1982 年 98 巻 1135 号 p. 939-946

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This work has been undertaken to demonstrate an inhibiting effects of some surfactants on spontaneous combustion of coals. Ignition temperature of coals, carbon monooxide production and oxygen consumption during an oxidation process of coals co-existing with surfactant were measured.
The conclusions drawn from these experiments are as follows;
1) Some surfactants have a certain good influence on ignition temperature of coals, but the magnitude of rising trends are different with varieties of surfactant and coal.
2) In oxidizing process of coals co-existing with a surfactants. a sudden increase in carbon monooxide production were observedatVicertaintemperature (about 150°C). The cafbon monooxide concentration and its production state at that time depended mainly on the used surfactant.
3) Judging from each experimental result, the sudden produciton of carbon monooxide are caused by decomposition of surfactant with consumption of oxygen.
4) A utility of surfactant as an inhibitor can be distinguished in relatively low temperature, In an extent from ambient temperature (room temperature) to about 100°C, the thicker the surfactant are used, the higher the efficiency is.

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