Indoor Environment
Online ISSN : 2186-4322
Print ISSN : 1882-0395
ISSN-L : 1882-0395
Investigation Notes
Indoor Air Pollution by 2-Butanone Oxime emitted from Silicone Sealant
Tokuko TSUNODAAya ONUKITomoko OKUBOIkue SAITOToshinari SUZUKIMitsugu HOSAKA
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JOURNAL OPEN ACCESS

2016 Volume 19 Issue 2 Pages 131-137

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Abstract
The process of monitoring of volatile organic compounds present in indoor air at a newly constructed building was undertaken in 2015. We detected 2-butanone oxime at a maximum concentration of 3,570 g/m3. The emission source of 2-butanone oxime was silicone sealant used in the construction of the building. The adsorption of 2-butanone oxime with thermal desorption using a Tenax TA sampler was suitably accurate to trap 2-butanone oxime under both low- and high- humidity conditions. It was confirmed that 2-butanone oxime was stable under high humidity (relative humidity: 80%), and the Tenax TA sampler, with a flow rate of 0.1 L/min, was able to stably measure data for 2 h. The emission source of both 2-butanone oxime and 2-butanone was a silicone sealant used in the building. This was determined by placing a glass plate coverd with the silicone sealant in a Tedlar® Bag for 2 weeks, and analyzed by Gas chromatograph/Mass spectrometer (GC/MS). Air in a Tedlar® Bag was sampling every other day throughout the 2-week period. A maximum concentration of 2-butanone oxime was observed after approximately 1 week, and it gradually decreased thereafter. The concentration of 2-butanone in the bag gradually increased throughout the sampling period; however, its production rate was low in comparison to the decline rate of 2-butanone oxime.
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© 2016 Society of Indoor Environment, Japan
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