The Journal of Silk Science and Technology of Japan
Online ISSN : 1881-1698
Print ISSN : 1880-8204
ISSN-L : 1880-8204
Crystallization Behavior of Silk Fibroin in the Presence of Sericin Fractions
Yutaka Kawahara
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2014 Volume 22 Pages 39-45

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Abstract

Gel-like liquid silk samples were collected from the middle division of the silk glands of fully grown larvae of domestic Bombyx mori silkworm 1 day before spinning or cocooning. The samples were then immersed in distilled water and kept at 4°C in a refrigerator for 2 days, during which time the fibroin and sericin molecules gradually dissolved into the water. The liquid silk solution was then cast on a polystyrene dish and dried at 4°C. The as-cast films were subjected to water annealing or immersion in ethanol, or both, and the crystallization behavior of the fibroin fraction was analyzed by wide-angle X-ray measurement. Normally the fibroin shows two types of crystal morphology—silk I or silk II—depending on the crystallization temperature. In the case of liquid silk containing both fibroin and sericin fractions, the fibroin molecules had a silk II crystal morphology after water annealing treatment at room temperature, whereas usually silk I crystal morphology would have been generated if only the fibroin molecules had been treated. A certain mechanism established between the fibroin and sericin fractions seems to have controlled the crystallization behavior of the fibroin.

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© 2014 by The Japanese Society of Silk Science and Technology
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