耐火物
Online ISSN : 2759-3835
Print ISSN : 0039-8993
ギブサイトと酢酸マグネシウムからのウイスカー状スピネル(MgAl204)の合成
藤吉 加一石田 信伍竹内 信行南里 隼人
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ジャーナル フリー

2001 年 53 巻 9 号 p. 506-515

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抄録
Whisker-like boehmite crystals with high aspect ratios were hydrothermally synthesized from gibbsite in magnesium acetate (Mg(CH3COO)2;MgAc2) solution,and they were used as a component of a precursor of MgAl204 spinel. The precursor of the spinel was a mixture of Mg-doped boehmite,MgAc2 deposited on boehmite and small quantities of unknown compounds.The precursor was heated at 500-1200℃ for 1h in air. The spinel was formed lust after the decomposition of MgAc2 into activated MgO by the reaction between the boehmite and the MgO without accompanying the formation of γ-Alumina phase.The spinel formation occurred at a temperature as low as 500℃ in air.
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© 2001 耐火物技術協会
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