炭素
Online ISSN : 1884-5495
Print ISSN : 0371-5345
ISSN-L : 0371-5345
黒鉛層間でのアニオン重合に対する有機溶媒の効果
塩山 洋
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2000 年 2000 巻 191 号 p. 20-23

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KC24 was allowed to react with the unsaturated hydrocarbon-organic solvent mixtures. Isoprene molecules were introduced into the interlayer of KC24 and polymerized, whereupon organic solvents such as cyclohexane, n-hexane or 2, 5-dimethyltetrahydrofuran was incorporated into the polyisoprene. On the other hand, the polymerization of styrene in the interlayer spacing of graphite was carried out without the incorporation of n-hexane or 2, 5-dimethyltetrahydrofuran. This is explained on the basis of the low affinity of aromatic styrene for aliphatic solvents. The polymerization of styrene was not observed in the presence of cyclohexane, which is attributed to a low reactivity of styrene to polymerize in the interlayer spacing of graphite.
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