炭素
Online ISSN : 1884-5495
Print ISSN : 0371-5345
ISSN-L : 0371-5345
木炭の高温加熱処理に伴う曲げ強度と微細構造の変化
川村 和郎天利 光宜有賀 敦小澤 真一郎
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2000 年 2000 巻 191 号 p. 32-36

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The relationship, σ=aρn was recognized between bending strength (σ) and bulk density (ρ) of the heat-treated charcoals at various heat treatment temperatures (HTT) below 2500°C, and the exponent (n) was almost constant (n=1.3). Usually, the bending strength of carbon materials decreases by the proceeding of graphitization with temperature heat treatment. On the other hand, the bending strength of the bincho-tan manufactured by carbonization of oak (ubamegashi) ncreased with increasing HTT. The specific surface area of the powdered samples decreased with increasing HTT and converged to a value near 80m2/g at HTT 2500°C regardress of the different texture of charcoals. The small angle X-ray scattering (SAXS) data of the heat-treated charcoals showed that the micropores of R=10-50 nm (R Guinier radius) almost disappeared with high temperature treatment.
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