高炉下部におけるプラスチック粒子の移動挙動

抄録

Injection of plastics into blast furnaces as an alternative reducing agent has been carried out for the purpose of mitigation of carbon dioxide emissions. Several studies on the pyrolysis of plastic particles have been reported, however flow behavior of plastic particles or unburnt char in actual blast furnace is not clear.
In this study, hotmodel experiments and thermogravimetry analysis were conducted for the modeling of gasification behavior of plastic particles, then flow behavior of plastic particle and unburnt char in a blast furnace was calculated by numerical simulation. According to the observation results of gasification experiment, volatile matter of plastics seems to be evolved at the surface of the particles. Regarding reaction of char derived from plastics, thermogravimetry analysis showed that rate of gasification of unburnt char depended on the rate of heating. Gasification rate in the case of rapid heating condition tended to increase.
As the results of numerical simulations, initial diameter of plastics and char diameter determined the flow behavior in the blast furnace. When relatively small plastic was injected or diameter of unburnt char was small, unburnt char went upward along with gas flow and most of it might be consumed at the cohesive zone. On the other hand, when relatively coarse plastics was injected and diameter of unburnt char was relatively coarse, it was suggested that unburnt char accumulated around the deadman.
Therefore, it is considered that fine plastics injection is desirable for the stable operation of blast furnace.