CO₂-Ar混合ガスによる溶鉄の脱炭と共存元素の酸化について

抄録

The rates of decarburization of molten iron, containing Si, Cr and Mn, with CO₂-Ar mixtures at 1600°C were measured, and the oxidations of the above-mentioned elements were also investigated. It was observed that the carbon concentration decreases linearly with time down to the critical value, C_f, where the oxide film appears on the surface of melt, and that the value of C_f increases with the amount of added elements and the partial pressure of CO₂. The critical value C_f depends on the deoxidizing force of added elements. Carbon concentration on the reaction interface, Ci, corresponding to C_f, calculated from the equilibria, Me+O=(MeO) and C+O =CO, was used to estimate the thickness of diffusion layer in metal surface. Before the oxide film appears on the surface of melt, the rates of decarburization was proportional to the partial pressure of CO₂ and independent of the amount and the kinds of added elements.