Synthesis of Tetrathiafulvalene-Functionalized Organic-Metal Hybrid Polymer

抄録

The electrochemically-active ligand has synthesized, in which the tetrathiafulvalene module is introduced at the 6-position of 1,4-di(2,2':6',2"-terpyridin-4'-yl)benzene (TTF-bTP). The synthesis was confirmed by MALDI-TOF MS and ¹H NMR. The organic-metal hybrid polymer consisting of TTF-bTP and Fe(II) was prepared. The formation of the hybrid polymer was monitored by UV-Vis spectrum titration and confirmed the polymeric objects by atomic force microscopy (AFM).