Transactions of the Materials Research Society of Japan
Online ISSN : 2188-1650
Print ISSN : 1382-3469
ISSN-L : 1382-3469
Structure Refinement of the Partially Dehydrated Natural Chabazite Cal.57Na0.49Al3.39Si8.55O24·11.53H2O
Akihiko NakatsukaHironao OkadaKeiko FujiwaraNoriaki NakayamaTadato Mizota
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2008 年 33 巻 4 号 p. 907-910

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Structure analysis of a slightly partially-dehydrated natural chabazite was carried out using single crystal X-ray diffraction. The presences of the five water sites and four exchangeable-cation sites, found in the fully hydrated sample investigated by our recent study (Nakatsuka et al., 2007), were also confirmed in the present partially dehydrated sample. The final structure refinement converged to R = 0.0280 and Rw = 0.0284 for 926 reflections. The occupancy of the water site located at the center of the 8-ring window in the [412 62 86]-cavity decreases significantly compared with that in the fully hydrated sample.
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© 2008 The Materials Research Society of Japan
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