Transactions of the Materials Research Society of Japan
Online ISSN : 2188-1650
Print ISSN : 1382-3469
ISSN-L : 1382-3469
Monomolecular Layer Formation of Amphiphilic Chromoionophore I at the Air/Water Interface
Noriyuki Ishii
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2009 年 34 巻 1 号 p. 1-8

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Monolayer formation and behavior on a water surface of chromoionophore I (ETH 5294), a lipophilic isologue of oxazine-dye Nile Blue, were studied on the basis of surface pressure-molecular area (π-A) isotherms. Chromoionophore I formed a Langmuir-Blodgett film, and the stability of the monolayer appears to depend on the subphase pH as well as the degree of protonation in the chromoionophore I molecule. The chromoionophore I monolayers on the surface of subphase which was slightly basic showed favorite relaxation profiles, while it appeared to be hard and fragile on the acidic subphase. Adsorption experiment with ferritin has demonstrated the utility of chromoionophore I monolayer as a potential template although parameters which dictate the suitable conditions have to be further optimized to obtain a highly densely packed protein array.
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© 2009 The Materials Research Society of Japan
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