Syntheses and Structures of Keggin-Type Polyoxometalate Crystals Hybridized with a Polymerizable Ionic-Liquid

Saki Otobe; Yoshiki Kiyota; Tatsuhiro Kojima; Yoshiki Oda; Shinichi Koguchi; Yosuke Okamura; Masashi Higuchi; Masaki Kawano; Yu Nagase; Takeru Ito

doi:10.14723/tmrsj.46.15

Regular Papers

Syntheses and Structures of Keggin-Type Polyoxometalate Crystals Hybridized with a Polymerizable Ionic-Liquid

Saki Otobe, Yoshiki Kiyota, Tatsuhiro Kojima, Yoshiki Oda, Shinichi Koguchi, Yosuke Okamura, Masashi Higuchi, Masaki Kawano, Yu Nagase, Takeru Ito

著者情報

キーワード: Inorganic-organic, Hybrid crystal, Polymerizable, Ionic-liquid, Polyoxometalate

ジャーナルフリー

2021 年 46 巻 1 号 p. 15-18

DOI https://doi.org/10.14723/tmrsj.46.15

[Correction] J-STAGE : tmrsj 46 1 pp.e1

詳細

抄録

Keggin-type polyoxometalate clusters were successfully hybridized with a polymerizable ionic-liquid having methacryloyl group and imidazolium moieties (denoted as MAImC₁). Metatungstate ([H₂W₁₂O₄₀]⁶⁻, H₂W₁₂) and dodecamolybdophosphate ([PMo₁₂O₄₀]³⁻, PMo₁₂) anions were firstly employed to obtain inorganic-organic hybrid crystals. Their compositions and structures were clearly revealed by single crystal structure analyses.

責任著者(Corresponding author)

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