2022 Volume 17 Issue 4 Pages 335-347
Aluminum alloy sliding components are widely used in internal combustion engines. However, aluminum easily adheres to the countersurface, resulting in high friction. Hence, laser irradiation was used to oxidize the aluminum surface and promote tribofilm formation using molybdenum dithiocarbamate and zinc dialkyldithiophosphate (ZnDTP). This study investigated laser irradiation to reduce friction between steel balls and aluminum disks in fully formulated engine oil. Laser scanning was used to create 100-μm-pitch concentric circles on the disks. The friction behavior was classified into two modes: no friction reduction (mode-I, μ: 0.09–0.12) and friction reduction after the high-friction period (mode-II, μ: 0.06–0.09). Friction mode transition occurred when the laser energy density exceeded the critical value (Ec). Energy-dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy showed that, for mode-I, aluminum adhered to the ball, and no sulfur-containing tribofilm formed. For mode-II, the ZnDTP-derived phosphate film formed on the disk suppressed aluminum adhesion, and a sulfur-containing tribofilm formed on the ball. Micro-Vickers tests and X-ray diffraction showed that an amorphous/nanocrystalline structure formed in the unirradiated area owing to heat diffusion under high-energy-density laser irradiation (>Ec). Results suggest that metallographic structural change in the unirradiated area promotes ZnDTP reactions, causing the mode transition.
