VITAMINS
Online ISSN : 2424-080X
Print ISSN : 0006-386X
STUDIES ON THE DECOMPOSITION PRODUCTS OF RIBOFLAVIN AND THEIR RELATED COMPOUNDS : (III) A STUDY OF PHOTOLYSIS OF RIBOFLAVIN IN ALKALINE SOLUTION
Kazuo HOTTAShuichiro INA
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JOURNAL FREE ACCESS

1959 Volume 16 Pages 576-579

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Abstract
By the photolysis of riboflavin in alkaline medium, lumiflavin was formed which is decomposed further to 3,4-dihydro-3-keto-4,6,7-trimethyl-2-quinoxaline carboxylic acid (lumiflavin-keto acid) by alkali. Lumiflavin-keto acid is further converted methyloxoviolet after 94 hours at room temperature in the presence of hydrogen peroxide in alkaline solution. Methyloxoviolet was proved to be identical with 4,6,7-trimethyl-2,3-dioxotetrahydroquinoxaline synthesized from 1,2-dimethyl-4-amino-5-methylaminobenzene.
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© 1959 THE VITAMIN SOCIETY OF JAPAN

この記事はクリエイティブ・コモンズ [表示 - 非営利 - 改変禁止 4.0 国際]ライセンスの下に提供されています。
https://creativecommons.org/licenses/by-nc-nd/4.0/deed.ja
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