X-ray Structure Analysis Online
Online ISSN : 1883-3578
ISSN-L : 1883-3578
Part 3
Synthesis and Crystal Structure of 5,15-Bis(3,5-di-tert-butylphenyl)-10-(phenylethynyl)-20-(trimethylsilylethynyl)porphyrin
Atul P. SINGHHee-Joon KIM
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Supplementary material

2010 Volume 26 Pages 23-24

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Abstract
The crystal structure of the title compound, C61H66N4Si(I) displays a highly unsymmetric molecular entity involving three different substituents on the meso-positions. The molecular units in the crystal are intermolecularly bonded to each other via π-π, and CH-π interactions, resulting in the genesis of a 2D structural motif. This compound crystallizes in the triclinic system of the P1 space group with the following cell parameters: a = 8.9729(10), b = 19.167(2), c = 20.763(2)Å; α = 65.932(2)°, β = 81.356(2)°, γ = 86.051(2)°, Z = 2.
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© 2010 by The Japan Society for Analytical Chemistry
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