Synthesis and Crystal Structure of a Chain Complex of Molybdenum(II) Acetate and 1,2-Bis(4-pyridyl)ethane Aiming at N2-Adsorption Property

Masahiro MIKURIYA; Noriaki KAIHARA; Junya YAMAMOTO; Shohei TAKADA; Daisuke YOSHIOKA; Hidekazu TANAKA; Makoto HANDA

doi:10.2116/xraystruct.29.31

Part 8

Synthesis and Crystal Structure of a Chain Complex of Molybdenum(II) Acetate and 1,2-Bis(4-pyridyl)ethane Aiming at N₂-Adsorption Property

Masahiro MIKURIYA, Noriaki KAIHARA, Junya YAMAMOTO, Shohei TAKADA, Daisuke YOSHIOKA, Hidekazu TANAKA, Makoto HANDA

Author information

Masahiro MIKURIYA
Department of Chemistry and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University
Noriaki KAIHARA
Department of Chemistry and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University
Junya YAMAMOTO
Department of Chemistry and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University
Shohei TAKADA
Department of Chemistry and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University
Daisuke YOSHIOKA
Department of Chemistry and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University
Hidekazu TANAKA
Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University
Makoto HANDA
Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University

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Supplementary material

2013 Volume 29 Pages 31-32

DOI https://doi.org/10.2116/xraystruct.29.31

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Abstract

The title compound, a chain adduct of molybdenum(II) acetate with 1,2-bis(4-pyridyl)ethane (bpe), catena(tetrakis(μ-acetato-O,O′)(μ-1,2-bis(4-pyridyl)ethane-N,N′)dimolybdenum(II)), [Mo₂(CH₃CO₂)₄(bpe)]_n, was synthesized, and the crystal structure was determined by the single-crystal X-ray diffraction method at 293 K. It crystallizes in the triclinic space group P1 with a = 7.8313(12)Å, b = 8.5393(13)Å, c = 9.9498(14)Å, α = 73.412(3)°, β = 68.894(2)°, γ = 73.198(3)°, V = 581.86(15)Å³, D_x = 1.747 g/cm³, and Z = 1. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0309 and 0.0680, respectively, for all 2580 independent reflections. The molecule has a zigzag chain structure with an alternating arrangement of Mo₂(CH₃CO₂)₄ [Mo-Mo 2.0984(5)Å] and bpe. The adsorption isotherm was investigated, and no adsorption property was found for N₂.

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