Crystal Structure of (Z)-1-[4-(Trifluoromethyl)benzylidene]thiosemicarbazide

Abstract

The compound of (Z)-1-[4-(trifluoromethyl)benzylidene]thiosemicarbazide crystallizes in the triclinic space group P1 and Z = 2 with cell parameters a = 7.0109(8)Å, b = 11.7862(13)Å, c = 14.9095(16)Å, α = 111.814(2)°, β = 91.720(2)°, γ = 101.036(2)° and V = 1115.7(2)ų. The crystal structure was solved by direct methods and refined by full-matrix least-squares on F² to final values of R1 = 0.0438 and wR2 = 0.1078. In the crystal, each molecule is linked by intermolecular N–H···S hydrogen bonds.