Crystal Structure of μ-Phenoxo-μ-benzoate-bridged Dinuclear Fe(II) Complex with a Dinucleating Ligand Having a Sterically Bulky Imidazolyl Group

Yuichi YASUDA; Hideki FURUTACHI; Yosuke HAYASHI; Kana ISHIZAKI; Shuhei FUJINAMI; Shigehisa AKINE; Masatatsu SUZUKI; Shigenori NAGATOMO; Teizo KITAGAWA

doi:10.2116/xraystruct.35.11

Part 3

Crystal Structure of μ-Phenoxo-μ-benzoate-bridged Dinuclear Fe(II) Complex with a Dinucleating Ligand Having a Sterically Bulky Imidazolyl Group

Yuichi YASUDA, Hideki FURUTACHI, Yosuke HAYASHI, Kana ISHIZAKI, Shuhei FUJINAMI, Shigehisa AKINE, Masatatsu SUZUKI, Shigenori NAGATOMO, Teizo KITAGAWA

著者情報

Yuichi YASUDA
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
Hideki FURUTACHI
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
Yosuke HAYASHI
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
Kana ISHIZAKI
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
Shuhei FUJINAMI
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
Shigehisa AKINE
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
Nano Life Science Institute (WPI-NanoLSI), Kanazawa University
Masatatsu SUZUKI
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
Shigenori NAGATOMO
Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba
Teizo KITAGAWA
Picobiology Institute, Graduate School of Life Science, University of Hyogo

ジャーナルフリー
電子付録

2019 年 35 巻 p. 11-13

DOI https://doi.org/10.2116/xraystruct.35.11

詳細

抄録

The structure of the dinuclear Fe(II) complex [Fe₂(Ph-bimp)(PhCO₂)(CH₃CN)](BF₄)₂·2CH₃CN·3CH₃CH₂OH (1) was determined by X-ray crystallography, where Ph-bimp is 2,6-bis[bis{2-(1-methyl-4,5-diphenylimidazolyl)methyl}aminomethyl]-4-methylpenolate. The compound crystallizes in a monoclinic space group Cc with a = 15.5690(10), b = 23.8260(8), c = 24.821(1)Å, β = 95.3460(3)°, Z = 4, V = 9167.2(10)Å³. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0336 and 0.0850, respectively, for all 16812 independent reflections. The complex has a μ-phenoxo-μ-benzoate-bridged diiron(II) core structure.

責任著者(Corresponding author)

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