Part 12
Synthesis and Crystal Structure of Bis{2-[(2-hydroxymethylphenyl)iminomethyl]-4-nitrophenolato}nickel(II) Monoacetonitrile
2021 年 37 巻 p. 85-86
詳細
2021 年 37 巻 p. 85-86
The title compound, [Ni(HL1–NO2)2]·CH3CN, [H2L1–NO2 = 2-[2-(hydroxymethylphenyl)iminomethyl]-4-nitrophenol], was synthesized and characterized by single-crystal X-ray analysis. The compound crystallizes in the triclinic space group P1 with cell parameters a = 10.556(2)Å, b = 11.779(3)Å, c = 12.247(3)Å, α = 86.412(10)°, β = 71.135(8)°, γ = 73.009(8)°, V = 1377.2(5)Å3, Dcalcd = 1.549 g/cm3, Z = 2. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0362 and 0.1024, respectively, for all 5989 independent reflections. The tridentate ligands coordinate to the nickel atom as a mer-manner.
