有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
Review de Debut
Palau'amineの全合成にみる合成設計
浅川 倫宏
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ジャーナル オープンアクセス

68 巻 (2010) 10 号 p. 1069-1070

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Recently, total synthesis of Palau’amine and its analogues, polycyclic dimeric pyroole-imidazole alkaloid, has been accomplished by Phil, S. Baran and co-workers. These alkaloids contain closely functionalized polycyclic rings and structurally complicated aminal moieties. Generally, the regio- and stereo-selective constructions of aminal moieties are difficult to control, because of its stability and reactivity. In this review, it will be focused on the strategy for the construction of aminal moieties in a later stage of the synthesis, and discussed about his novel and artful synthetic plan making a new wave continually.

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© 2010 社団法人 有機合成化学協会
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