J-STAGE トップ  >  資料トップ  > 書誌事項

有機合成化学協会誌
Vol. 70 (2012) No. 8 p. 854-855

記事言語:

http://doi.org/10.5059/yukigoseikyokaishi.70.854

Review de Debut

Recent progress in asymmetric synthesis based on the formation of chiral boron “ate” complex is overviewed. Hoppe and Aggarwal have reported stereo-controlled homologation of chiral boron “ate” complex via stereoselective 1,2-rearrangement. Aggarwal has also observed the inversion of stereochemistry during the formation of boron “ate” complex, in the reaction of sterically-hindered chiral carbanion with boronic acid ester. These results will provide a new direction to the field of asymmetric synthesis.

Copyright © 2012 社団法人 有機合成化学協会

記事ツール

この記事を共有