Journal of Synthetic Organic Chemistry, Japan
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
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Development of New Chiral Brønsted Acid Catalysis
Shin-ichi HirashimaHisashi Yamamoto
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JOURNAL OPEN ACCESS

2013 Volume 71 Issue 11 Pages 1116-1125

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Abstract
Brønsted acid catalysis has received considerable attention in modern organic synthesis. However, the utility of these Brønsted acid catalysts are somewhat limited toward applicable substrates due to its relatively lower reactivities of these Brønsted acids. With these perspectives, it is highly desirable to develop Brønsted acids demonstrating both high reactivities and selectivities. In this feature article, we will describe our achievement in the design and development of Lewis acid assisted Brønsted acid catalysts (LBA), Brønsted acid assisted Brønsted acid catalysts (BBA), strong Brønsted acid catalysts, and their applications.
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© 2013 The Society of Synthetic Organic Chemistry, Japan
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