有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
総説および総合論文
混合試料解析に有効なDOSY NMR
櫻井 智司
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ジャーナル 認証あり

2014 年 72 巻 5 号 p. 604-610

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抄録
NMR (Nuclear Magnetic Resonance) is a useful tool to analyze products of chemical synthesis. However, when by-products are synthesized simultaneously, analyses by NMR become a challenge due to spectral overlapping of each component. For analyses of such mixtures by NMR, very useful method DOSY (Diffusion Ordered SpectroscopY) was proposed in 1990’s. It enables to separate spectra of mixtures into each component by using the difference of individual self diffusion coefficients. In this article, I introduce DOSY from its principle to practical experiments, and show an example of application for analysis of reaction pathway.
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© 2014 社団法人 有機合成化学協会
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