有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
総説および総合論文
中国横断山脈地域に生育するキク科Ligularia属植物の生産するフラノエレモフィラン化合物の多様性
黒田 智明花井 亮通 元夫岡本 育子齋藤 義紀永野 肇大崎 愛弓廣田 洋河原 孝行龔 洵
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2014 年 72 巻 6 号 p. 717-725

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A series of our studies on the chemical and genetic diversity of Ligularia species in the Hengduan Mountains area of China is reviewed. Diversities were detected in various species in terpenoid compositions and DNA sequences of the ITS region. Furanoeremophilanes were isolated from many species together with eremophilan-8-ones. Samples of some species such as L. virgaurea were grouped into two or more chemotypes, while L. cymbulifera and L. cyathiceps were uniform. Complex diversity was found in L. kanaitzensis. A hypothesis that the production of furanoeremophilanes is ecologically advantageous was proposed. Production of terpenoids in L. duciformis and related species were suggested to be acquired by hybridization which may be one of the major pathways of the evolution of Ligularia. Some taxonomically close species, such as L. lamarum and L. subspicata, were indistinguishable in both the root chemicals and the ITS sequences.
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© 2014 社団法人 有機合成化学協会
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