総説および総合論文
パラジウム触媒を用いたプロパルギルエステルと求核剤の環化反応による環状化合物の選択的合成
2017 年 75 巻 1 号 p. 38-48
詳細
2017 年 75 巻 1 号 p. 38-48
Palladium-catalyzed cyclization of propargylic esters with bis-nucleophiles is one of the useful method for the construction of cyclic molecules in one step. A variety of products could be synthesized in one step by the choice of adequately designed nucleophilic molecules. In this review, we describe a comprehensive overview of our studies on palladium-catalyzed reactions of propargylic esters with bis-nucleophiles. The reactions afforded various functionalized hetero- and carbocyclic molecules in a regio- and stereoselective manner.
