芳香環縮環ジケトホスファニル骨格をコアとする機能性π共役分子の創製

抄録

π-Conjugated organophosphorus compounds represented by phospholes serve as unique building blocks and functional cores for various organic functional materials, due to the unique features such as σ^＊-π^＊ hyperconjugation and P-modulability. Therefore, the development of novel π-conjugated organophosphorus building blocks and core scaffolds would be of great importance to open up new horizons of phosphorus-containing functional materials. Recently, we have revisited missing pieces of organophosphorus compounds, i.e., aromatic-fused diketophosphanyl compounds, and cultivated their potential use as building blocks for functional organic materials. In this account, our contributions to the development of diketophosphanyl-cored organic materials are described.