金（I）錯体への酸化的付加を起点とするカップリング反応

抄録

Gold-catalyzed reaction initiated by π-activation of unsaturated bonds is well-established, where the oxidation state of the gold complex is unchanged throughout the catalytic cycle. Recently, the coupling reactions involving Au(I)/Au(III) catalytic cycle have been developed. The key to success is the kinetic or thermodynamic stabilization of Au(III) species. This mini-review focuses on the generation of Au(III) species by direct oxidative addition of carbon-halogen bond to Au(I) and their application to coupling reactions.