Journal of Synthetic Organic Chemistry, Japan
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
Chloromethylation of Anthraquinoneacridones,
Syo NAKAZAWA
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1962 Volume 20 Issue 7 Pages 661-667

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Abstract
Chloromethylation of anthraquinonebenzeneacridone and anthraquinonenaph thaleneacridone with sym-dichlorodimethylether in the presence of concentrated sulfuric acid gave mono- and bis-chloromethyl compounds from the former and mono-, his- and trichloromethyl compounds from the latter almost in pure form. The chloromethyl group was first entered into 12-position of anthraquinone benzeneacridone, to give mono chloromethyl compound then it entered into 10-position to give a bis (chloromethyl) compound. These chloromethylated compounds were derived into pyridinium and isothiuronium salts and their dyeing qualit properties were examined.
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© The Society of Syhthetic Organic Chemistry, Japan
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