有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
アミノ-s-トリアジン類と芳香族アミン類との反応(第3報)
アンメリドと塩酸アニリンとの反応
本田 格北川 修一
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ジャーナル フリー

1962 年 20 巻 8 号 p. 765-767

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Reaction of ammelide and aniline hydrochloride in the molar ratio of 1: 4 for 2 hr S. at 190°c yielded 73% N-phenylammelide, mp 313-4°c (d), from alkalisoluble portion, and its alkali-insoluble portion yielded 10% of N, N'-diphenylurea. The structure of N-phenylammelide was confirmed by the mixed fusion with the product obtained by hydrolysis of 2-anilino-4, 6-dichloro-s-triazine. Reaction for long period of time at high temperature did not give N-phenylammelide but gave N, N'-diphenylammeline from alkali-soluble portion, together the formation of large amount of N, N'-diphenylurea, with the indication that the triazine ring in ammelide type compound is easily decomposed by opening of its ring.
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