Journal of Synthetic Organic Chemistry, Japan
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
Reaction of Triethylaluminum with Acid Chlorides
Yoshio BABA
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1969 Volume 27 Issue 1 Pages 47-50

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Abstract
The reaction of free triethylaluminum with carboxylic acid chloride was reported to give a complicated condensation product. In the present study, it has been found that by using a diethyl ether adduct of triethylaluminum, the reaction can be terminated at the stage of monomeric alcohol formation. Attempts to isolate ketones, however, failed to succeed even when sterically hindered acid chloride was used.
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© The Society of Syhthetic Organic Chemistry, Japan
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