Journal of Synthetic Organic Chemistry, Japan
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
Synthesis of Bis-lactone Compounds and Application to Heat Sensitive Copying Paper
Fumio OKUMURAKiyoshi FUTAKI
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1976 Volume 34 Issue 2 Pages 100-103

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Abstract
It was found that equimolecular reaction of 2- (4'-diethyl-amino-2'-hydroxybenzoyl) benzoic acid (DHBB) and 4-hydroxy-N-methyldiphenylamine (HMDA) gave not only 3-diethylamino-7- (N-methylanilino) fluorane (1) but also a bis-lactone compound (2) which was given by further reaction of (1) with DHBB. The chemical structure of this bis-lactone compound (2) was determined and this was synthesized in good yield from 2 moles of DHBB and 1 mole of HMDA. Several compounds having the bis-lactone structure were synthesized and some of them were found to be useful in industrial application, such as pressure or heat sensitive copying paper.
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© The Society of Syhthetic Organic Chemistry, Japan
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