アニリン類のオルト特異的フリーデル・クラフツ反応
1978 年 36 巻 6 号 p. 480-491
詳細
1978 年 36 巻 6 号 p. 480-491
A new general process has been developed for specific ortho hydroxybenzylation of secondary anilines and specific ortho acylation of anilines using anilinodichloroboranes. The distinctive exchange of the reaction site of anilines in the presence of boron trichloride instead of other electrophilic metal halide is very noteworthy. The mechanistic hypothesis, scope and limitations and application are described.
